the fuel cells are distinguished as generating of green allocable energy and are electrochemical devices of low environmental impact. porous nanocrystalline strontium-doped lanthanum manganite la0.8sr0.2mno3 (lsm) cathode materials were prepared by mechanochemical route in various grinding times. carbon black was employed to produce pores. the formation of lsm single phase was studied by x-ray ...

synthetic hydroxyapatite (ha) is the most helpful because of its similarity to natural bone in both crystalline structure and chemical composition. recently, fluoridated hydroxyapatite (fha) has been developed in dental and orthopedic application because it has lower solubility than pure ha, while maintaining the comparable bioactivity and biocompatibility. the aim of this study was to synthesi...

We provide the first in situ and real-time study of the effect of milling frequency on the course of a mechanochemical organic reaction conducted using a vibratory shaker (mixer) ball mill. The use of in situ Raman spectroscopy for real-time monitoring of the mechanochemical synthesis of a 2,3-diphenylquinoxaline derivative revealed a pronounced dependence of chemical reactivity on small variat...

        Synthetic hydroxyapatite (HA) is the most helpful because of its similarity to natural bone in both crystalline structure and chemical composition. Recently, fluoridated hydroxyapatite (FHA) has been developed in dental and orthopedic application because it has lower solubility than pure HA, while maintaining the comparable bioactivity and biocompatibility. The aim of this study was to...

Abstract: Nano- size alumina particles have been synthesized by mechanical activation of a dry powder mixture of AlCl3 and CaO. Mechanical milling of the above raw materials with the conditions adopted in this study resulted in the formation of a mixture consisting of crystalline CaO and amorphous aluminum chlorides phases. There was no sign of chemical reaction occurring during milling stag...

We demonstrate a mechanochemical strategy that allowed the first successful mechanosynthesis of IRMOFs based on an oxo-centred secondary building unit (SBU). The presented study indicates that controlling the acid-base relationship between reagents is key to mechanochemical synthesis of IRMOFs, revealing a pre-assembled oxo-zinc amidate cluster as an efficient precursor for IRMOF mechanosynthesis.

in the present work, we report the synthesis of binary nano metal oxides such as zinc /copper oxide via novel dry synthetic methods such as thermal decomposition of oxalate precursor. the synthesis route involves facile solid-phase mechanochemical activation of a physical mixture of simple copper/zinc salts and oxalic acid, followed by calcination of the as-ground oxalate precursors at 450◦c. x...